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Journal that the chemistry Society, Faraday Transactions 1: physical Chemistry in Condensed Phases


Depression of the freezing suggest of lithium through nitrogen and by hydrogen. Eutectic Compositions and also Solid Solubilities


The depressions of the freezing suggest of lithium (gettered by yttrium in ~ 400°C) led to by nitrogen and also hydrogen have actually been figured out by thermal analysis. For Li3N in lithium, the freezing allude drops significantly from 180.49 come 180.24°C in ~ the eutectic composition, 0.068 mol % N. For LiH, the maximum depression is 0.08°C and also the eutectic ingredient is 0.016 mol % H. The depression was used to calculate the hard solubility the N and H in lithium. Because that the liquid, the solubility that non-metal rises native the eutectic point to 0.070 and also 0.017 mol % N and H, respectively, at the melt point, 180.49°C. The data finish the metal-rich finish of the lithium-lithium salt phase diagrams.


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DOI https://doi.org/10.1039/F19767200431
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J. Chem. Soc., Faraday Trans. 1, 1976,72, 431-435
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Depression that the freezing allude of lithium by nitrogen and by hydrogen. Eutectic Compositions and also Solid Solubilities

P. Hubberstey, R. J. Pulham and A. E. Thunder, J. Chem. Soc., Faraday Trans. 1, 1976,72, 431 DOI: 10.1039/F19767200431

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Peter Hubberstey
Richard J. Pulham
ann E. Thunder

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