Hydrogen bromide (HBr) is a polar molecule becauseof the electronegativity difference in between Hydrogen (2.2) and also Bromine (2.96).Bromine is higher electronegative 보다 hydrogen so it attracts electron fromhydrogen, as a result, 2 dipole poles space induced because of this the molecule has a network dipole moment.

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Detailed Explanation: Why is HBr a Polar Molecule?

HBr whose chemical name is hydrogen bromide and its aqueous solution is well-known as hydrobromic acid, is a colorless to light yellow liquid whichis developed by one atom of hydrogen and one atom that bromine and considered a strongacid.


Now prior to entering deep into its polarity nature, very first wehave to understand what polar and nonpolar molecule are:

Polar Molecules

Polar molecules are simply defined as the visibility of a polar bondwithin the molecule or have actually irregular geometry (not symmetry structure), therefore the network dipole moment of the molecule is not zero as the facility of heaviness of negativecharge and also positive charge is be separated by a little distance.

These molecules are provided to show little ioniccharacteristics i.e. They room soluble in water, have the right to conduct electricity, havestrong electrostatic force and many more.

Examples of Polar molecules: Water (H2O), Hydrochloric acid(HCl), Ammonia (NH3), etc.

Nonpolar Molecules

Nonpolar molecule are just pure covalent bonded moleculeswith mutual sharing that electrons and also have network dipole moment zero. As there areno event of partial hopeful and negative charge top top the atoms since of the exact same electronegativity difference in between the atom (Diatomic molecules prefer H2,O2, N2, etc) or molecule has constant geometry (symmetrical molecules like CCl4,CO2 etc) so bond polarities space canceled by each other.

When Nonpolar molecules are placed in an electric field, thecenter of gravity of confident charge moves in direction the the field, and the center of the gravity of an adverse charge in the opposite direction. This separation betweenpositive and an adverse charges continues until the used external force andinternal force are balanced.

Example of Nonpolar molecules: all diatomic molecule (H2,N2, O2, Cl2, etc.), Carbon tetrachloride (CCl4), Carbon Dioxide (CO2), Xenon tetrafluoride (XeF4) etc.

HBr Polar or Nonpolar (On the basis of characteristics)

Hydrogen bromide (HBr) is a polar molecule and the Bromineatom closest to the negative side because bromine has a higher electronegativitythan hydrogen atom so the Bromine pulls the lone pair of electrons slightlycloser which reasons induction of confident charge ~ above H atom and an adverse charge onBr atom.

Here are several of the HBr features which intricate itspolarity nature why HBr is a polar molecule:

Electronegativity Difference

Electronegativity is a type of force exerted by one atom ormolecule at the time of bond development on the binding partner. It means an atomexerts a force on the equivalent bonding atom at the time of the sharing of a lonepair the electrons. The greater the electronegative value, the much more force will be exertedfor attracting the electrons. If two atoms having actually the very same EN worth exerted forceswill it is in canceled out.

In the HBr molecule,

Electronegativity the Hydrogen= 2.2

Electronegativity that Bromine= 2.96

Electronegativity difference= 2.96-2.2= 0.76

From the over data, the electronegativity difference between Hand Br is around 0.76 and also according to the Pauli scale, if the electronegativitydifference in between two atom is in between 0.5 come 2.0, the corresponding bond isconsidered together polar bond. Thus, the EN difference is 0.76, the H-Br bond is polar.

Lewis framework & molecule Geometry

HBr compound has a full of 8 valence electrons (electronson the outermost shell), one indigenous hydrogen and 7 from bromine which takes partin the formation of the Lewis period structure. Both atoms share one lone electron tofulfill their outermost covering at the time of bonding.


As HBr is a heteronuclear diatomic molecule, the moleculargeometry is linear with a bond edge of 180°which reasons the induced partialcharges perform not cancel each other and the molecule has a network dipole moment.

Dipole Moment

The dipole moment is a significant asset for any type of compound being polar or nonpolar. Those molecules having actually net dipole moment zero are taken into consideration as nonpolar molecules and also the rest are polar. Dipole moment have the right to be defined as the assets of induced charge and distance of separation. It is denoted by and given by,

Dipole minute = charge (Q) * street of separation (r)

It is measure up in Debye devices denoted through ‘D’. 1D = 3.33564*10-30 C.m, where C is Coulomb and also m denotes a meter.

Hydrogen bromide has actually a net dipole moment of 820 mD i beg your pardon arisesdue to the distinction in electronegativity between the hydrogen and also bromine andalso, the geometry that the molecule is linear.

Electron Affinity

Electron affinity is the possibility of detect an electron atthe orbit of one atom or molecule. That is difficult to recognize the exactposition of one electron at a particular time according to the uncertaintyprinciple. However we can just suspect the maximum chances of getting an electronaccording to the nature of the molecule or atom.

As HBr is a polar molecule, the maximum possibilities of gaining anelectron is higher closer to the bromine atom since it traction the lone pair ofelectrons closer to its nucleus. Yet in the nonpolar molecules, the maximum possibilities ofgetting one electron is greater at the main position the the bond.

Solubility Principle

According to the solubility rule “likes dissolve likes” meanspolar compounds space soluble in different polar solvents and also nonpolar solventsare dissolve in nonpolar solvents. Very same in the situation of HBr, it is soluble in waterwhich is a polar solvent to produce hydrobromic acid. Not only in water the caneasily be soluble in many an ext polar solvents like alcohol, ammonia, etc.

Sources and preparation of Hydrogen bromide (HBr)

For industrial purposes, Hydrogen bromide is all set by combininghydrogen and bromine at a temperature that 400°C in the presence of a platinumcatalyst.

In the laboratory, that is most generally prepared through distillationof potassium bromide v sulfuric acid.

KBr + H2SO4→KHSO4 +HBr

Properties the HBr

1. The is a colorless gas with a pungent irritating odor and hasa molecular mass that 80.91 g/mol.

2. It is very corrosive and irritating come inhalation for this reason thatit have to be handled really carefully otherwise reasons many serious problems.

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Uses of HBr (Hydrobromic acid)

It is supplied in plenty of chemical intermediate commodities assanitizing and disinfecting agent.Used in the preparation of numerous organic compounds as areagent and also catalyst.It is additionally used in a utility-scale flow-typebattery.